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Chlorosulfuric acid, chloromethyl ester

chloromethyl chlorosulphate

CAS: 49715-04-0

Molecular Formula: CH2Cl2O3S

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Chlorosulfuric acid, chloromethyl ester - Names and Identifiers

Name chloromethyl chlorosulphate
Synonyms CHLOROMETHYL CHLOROSULFATE
Chloromethyl chlorosulfate
Chloro chloromethyl sulfate
chloromethyl chlorosulphate
Chlorosulfuric acid, chloromethyl ester
chloro{[(chlorooxy)sulfonyl]oxy}methane
Chloridosulfuric acid chloromethyl ester
Chloridosulfuric acid (chloromethyl) ester
CAS 49715-04-0
EINECS 256-442-1
InChI InChI=1/CH2Cl2O4S/c2-1-6-8(4,5)7-3/h1H2
InChIKey PJBIHXWYDMFGCV-UHFFFAOYSA-N

Chlorosulfuric acid, chloromethyl ester - Physico-chemical Properties

Molecular FormulaCH2Cl2O3S
Molar Mass165
Density1.631 g/mL at 25 °C
Boling Point45-50 °C/10 mmHg
Flash Point176°F
Water Solubilityreacts
Vapor Presure0.267mmHg at 25°C
AppearanceLiquid
ColorClear colorless to yellow
Storage Condition2-8°C
Refractive Indexn 20/D 1.448
Physical and Chemical Properties
density 1.631
boiling point 45-50 °C (10 MMHG)
refractive index 1.446-1.448
flash 176 °F
water-soluble reaction

Chlorosulfuric acid, chloromethyl ester - Risk and Safety

Risk CodesR22 - Harmful if swallowed
R34 - Causes burns
R26 - Very Toxic by inhalation
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S28A -
UN IDsUN 1760 8/PG 3
WGK Germany3
HS Code29049090
Hazard Class8
Packing GroupII

Chlorosulfuric acid, chloromethyl ester - Reference Information

uses methyl chlorosulfonate compounds include chloromethyl chlorosulfonate and methyl dichlorosulfonate, which are important organic synthesis intermediates and a new type of high-efficiency and safe electrolyte for lithium batteries.
Preparation 1) Under the condition of -50~40 ℃, in the presence of catalyst carbonate, carbonate containing saturated hydrocarbon base, borate, and borate containing saturated hydrocarbon group, Liquid sulfur trioxide reacts with dichloromethane for 1~24 hours to produce a mixture of chloromethyl chlorosulfonate and methyl dichlorosulfonate; 2) Put sodium carbonate or sodium carbonate aqueous solution into the mixture obtained in the above step 1) to remove excess sulfur trioxide and sulfuric acid generated by moisture absorption, so that the reaction continues; 3) Put sodium bicarbonate or sodium bicarbonate aqueous solution into the mixture obtained in the above step 2), completely remove excess sulfur trioxide and sulfuric acid generated by moisture absorption, stand for stratification, take the upper organic layer to dry to remove the solvent, and distill under reduced pressure, chloromethyl chlorosulfonate and methyl dichlorosulfonate were obtained respectively.
Last Update:2024-04-10 22:29:15
Chlorosulfuric acid, chloromethyl ester
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Mobile: +86-17551318830
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Product Name: Chloromethyl chlorosulfate Request for quotation
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View History
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